Collect. Czech. Chem. Commun.
1980, 45, 584-598
https://doi.org/10.1135/cccc19800584
Solvolysis of 5,6β-cyclopropano-5β-cholestane-3β,19-diol 3-acetate 19-p-toluenesulphonate
Jan Fajkoša, Jiří Joskaa and František Turečekb
a Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague 6
b The Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 121 38 Prague 2
Abstract
Acetolysis of 5,6β-cyclopropano-5β-cholestane-3β,19-diol 3-acetate 19-ptoluenesulphonate afforded 5,6β-cyclopropano-5(10)a-homo-19-nor-5β-cholest-1(10)-ene-3β-ol 3-acetate and 7β,19-cyclo-B-homo-5α-cholestane-3β,5-diol 3,5-diacetate.The structures of these products were established by spectral and chemical means.
