Collect. Czech. Chem. Commun.
1984, 49, 1228-1239
https://doi.org/10.1135/cccc19841228
Liquid-liquid equilibrium, modelling the temperature dependence of mutual solubility of liquids
Josef P. Novák, Jaroslav Matouš and Jiří Pick
Department of Physical Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6
Abstract
The applicability of the modified Wilson equation to correlation of the temperature dependence of mutual solubility of liquids is demonstrated. The position of the critical point is fixed, and the linear dependence of parameters on temperature is used in calculating. The method was applied with success to the aqueous solutions of 1-butanol, isobutyl alcohol, phenol and 2-butanone and to the nonaqueous system cyclohexane-methanol.
