Collect. Czech. Chem. Commun.
1986, 51, 2013-2018
https://doi.org/10.1135/cccc19862013
Mechanism of alkenylation of aromatic substrates with 5-nitro-2-furylvinyl bromide
Ján Hrabovský, Jaroslav Kováč and František Považanec
Department of Organic Chemistry, Slovak Technical Institute, 812 37 Bratislava
Abstract
Mechanism has been studied of electrophilic aromatic substitution with (Z)- and (E)-5-nitro-2-furylvinyl bromide in the presence of aluminium(III) chloride. From chemical findings and 1H NMR study it follows that the mechanism can be interpreted as an electrophilic addition-elimination pathway (AdE-E) from the point of view of the vinyl substitution.
