Collect. Czech. Chem. Commun.
1987, 52, 1758-1763
https://doi.org/10.1135/cccc19871758
The kinetic study of the addition of tetrachloromethane to styrene in the presence of copper complexes
Li Gwang Hun and Lubomír Nondek
Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02 Prague 6-Suchdol
Abstract
Kinetics of the addition of tetrachloromethane to styrene catalyzed by copper-amine complexes was studied. The pseudo-first order kinetics in respect to styrene and the catalyst was observed at an excess of tetrachloromethane. The reaction mechanism involving a catalytic cycle compatible with the kinetic observations is proposed. The experimental activation energy, being about 104 kJ mol-1, indicates a catalytic mechanism.
