Collect. Czech. Chem. Commun.
1988, 53, 1268-1273
https://doi.org/10.1135/cccc19881268
Kinetics of alkaline hydrolysis of 3,4-thiophenedicarboxylic acid monomethyl ester in aqueous-nonaqueous media
Ján Benko and Oľga Vollárová
Department of Physical Chemistry, Comenius University, 842 15 Bratislava
Abstract
The kinetics of alkaline hydrolysis of 3,4-thiophenedicarboxylic acid monomethyl ester has been studied in mixed solvents water-methyl alcohol, water-tert-butyl alcohol, and water-dioxane. The specific effects causing different courses of these dependences have been evaluated. The greatest changes in the thermodynamic activation parameters have been observed in the medium of water-methyl alcohol.
