Crossref Cited-by Linking logo

Collect. Czech. Chem. Commun. 1996, 61, 691-703
https://doi.org/10.1135/cccc19960691

29Si NMR Study of Distribution of Oligomers in Polycondensation of Tetraethoxysilane

Jiří Brusa, Jiří Karhanb and Petr Kotlíka

a Department of Chemical Technology of Monuments Conservation, Prague Institute of Chemical Technology, 166 28 Prague 6, Czech Republic
b Central NMR Laboratory, Prague Institute of Chemical Technology, 166 28 Prague 6, Czech Republic

Crossref Cited-by Linking

  • Sato Yohei, Sugimoto Asahi, Iwashina Tatsuya, Hayami Ryohei, Yamamoto Kazuki, Gunji Takahiro: Hydrolysis and condensation behavior of tetraethoxysilane, hexaethoxydisiloxane, and octaethoxytrisiloxane. J Sol-Gel Sci Technol 2023, 108, 377. <https://doi.org/10.1007/s10971-023-06159-x>
  • Kapusuz Yavuz Derya: Exploring the structure of RNA-incorporated PEG/PEI modified silica network. Materials Chemistry and Physics 2022, 279, 125779. <https://doi.org/10.1016/j.matchemphys.2022.125779>
  • Krylova I. V., Egorov M. P., Nefedov O. M.: Reaction of silicon with alcohols in autoclave. Russ Chem Bull 2017, 66, 260. <https://doi.org/10.1007/s11172-017-1726-7>
  • Martinelli Anna: Effects of a Protic Ionic Liquid on the Reaction Pathway during Non-Aqueous Sol–Gel Synthesis of Silica: A Raman Spectroscopic Investigation. IJMS 2014, 15, 6488. <https://doi.org/10.3390/ijms15046488>
  • Beneš Hynek, Galy Jocelyne, Gérard Jean-François, Pleštil Josef, Valette Ludovic: Solvent-free synthesis of reactive inorganic precursors for preparation of organic/inorganic hybrid materials. J Sol-Gel Sci Technol 2011, 59, 598. <https://doi.org/10.1007/s10971-011-2534-4>
  • Spinde Katrin, Pachis Konstantinos, Antonakaki Ioanna, Paasch Silvia, Brunner Eike, Demadis Konstantinos D.: Influence of Polyamines and Related Macromolecules on Silicic Acid Polycondensation: Relevance to “Soluble Silicon Pools”?. Chem. Mater. 2011, 23, 4676. <https://doi.org/10.1021/cm201988g>
  • Depla Anouschka, Lesthaeghe David, van Erp Titus S., Aerts Alexander, Houthoofd Kristof, Fan Fengtao, Li Can, Van Speybroeck Veronique, Waroquier Michel, Kirschhock Christine E. A., Martens Johan A.: 29Si NMR and UV−Raman Investigation of Initial Oligomerization Reaction Pathways in Acid-Catalyzed Silica Sol−Gel Chemistry. J. Phys. Chem. C 2011, 115, 3562. <https://doi.org/10.1021/jp109901v>
  • Depla Anouschka, Verheyen Elke, Veyfeyken An, Van Houteghem Marc, Houthoofd Kristof, Van Speybroeck Veronique, Waroquier Michel, Kirschhock Christine E. A., Martens Johan A.: UV-Raman and 29Si NMR Spectroscopy Investigation of the Nature of Silicate Oligomers Formed by Acid Catalyzed Hydrolysis and Polycondensation of Tetramethylorthosilicate. J. Phys. Chem. C 2011, 115, 11077. <https://doi.org/10.1021/jp200568j>
  • Beckett Michael A., Rugen-Hankey Martin P., Varma K. Sukumar: Formation of borosilicate glasses from silicon alkoxides and metaborate esters in dry non-aqueous solvents. J Sol-Gel Sci Technol 2006, 39, 95. <https://doi.org/10.1007/s10971-006-8972-8>
  • Johnston Angus P. R., Battersby Bronwyn J., Lawrie Gwendolyn A., Lambert Lynette K., Trau Matt: A Mechanism for Forming Large Fluorescent Organo-Silica Particles:  Potential Supports for Combinatorial Synthesis. Chem. Mater. 2006, 18, 6163. <https://doi.org/10.1021/cm0526260>
  • Miller Chris R., Vogel Robert, Surawski Peter P. T., Jack Kevin S., Corrie Simon R., Trau Matt: Functionalized Organosilica Microspheres via a Novel Emulsion-Based Route. Langmuir 2005, 21, 9733. <https://doi.org/10.1021/la0514112>
  • Jaumann Manfred, Rebrov Eugene A., Kazakova Valentina V., Muzafarov Aziz M., Goedel Werner A., Möller Martin: Hyperbranched Polyalkoxysiloxanes via AB3‐Type Monomers. Macro Chemistry & Physics 2003, 204, 1014. <https://doi.org/10.1002/macp.200390067>
  • Brus J., Kolář F., Machovič V., Svı́tilová J.: Structure of silicon oxycarbide glasses derived from poly(methylsiloxane) and poly[methyl(phenyl)siloxane] precursors. Journal of Non-Crystalline Solids 2001, 289, 62. <https://doi.org/10.1016/S0022-3093(01)00735-9>
  • Brus J., Dybal J.: Copolymerization of tetraethoxysilane and dimethyl(diethoxy)silane studied by 29 Si NMR and ab initio calculations of 29 Si NMR chemical shifts. Polymer 1999, 40, 6933. <https://doi.org/10.1016/S0032-3861(99)00095-6>
  • Rankin Stephen E., Macosko Christopher W., McCormick Alon V.: Sol‐gel polycondensation kinetic modeling: Methylethoxysilanes. AIChE Journal 1998, 44, 1141. <https://doi.org/10.1002/aic.690440512>
  • Rankin Stephen E., Macosko Christopher W., McCormick Alon V.: Importance of Cyclization during the Condensation of Hydrolyzed Alkoxysilanes. Chem. Mater. 1998, 10, 2037. <https://doi.org/10.1021/cm980256s>
  • Brus Jiří, Kotlík Petr: Polyacrylate Effects on Tetraethoxysilane Polycondensation. Chem. Mater. 1996, 8, 2739. <https://doi.org/10.1021/cm9602407>