Collect. Czech. Chem. Commun.
1998, 63, 1-19
https://doi.org/10.1135/cccc19980001
Vanadyl Phosphate and Its Intercalation Reactions. A Review
Jaroslava Kalousováa, Jiří Votinskýa, Ludvík Benešb, Klára Melánováb and Vítězslav Zimab
a Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, 532 10 Pardubice, Czech Republic
b Joint Laboratory of Solid State Chemistry of the Academy of Sciences of the Czech Republic and University of Pardubice, 530 09 Pardubice, Czech Republic
Abstract
The structure of the layered αI-VOPO4, VOPO4·2H2O, and their intercalation reactions are discussed. These reactions are divided into two groups. The first includes intercalation reactions of molecular guests which proceed as acid-base processes between the host layered lattice (Lewis acid) and a donor atom of the guest (base). Interaction of water molecules, alcohols, amines, carboxylic acids and their derivatives, heterocyclic N- and S-donors, and complex compounds with vanadyl phosphates is discussed. Vanadyl phosphate, in particular vanadyl phosphate dihydrate can also undergo the second type of the reactions which involves the reduction of a fraction of vanadium(V) atoms to vanadium(IV) with concomitant intercalation of alkylammonium, hydronium or mono- and divalent metal cations to counterbalance the induced negative layer charge. A review with 76 references.
Keywords: Intercalation; Layered compounds; Vanadyl phosphate.
