Collect. Czech. Chem. Commun.
2000, 65, 1455-1463
https://doi.org/10.1135/cccc20001455
Transfer Thermodynamic Functions ∆Gt0, ∆Ht0 and T∆St0 of cis- and trans-[CoCl2(en)2]+ Isomers in Aqueous Mixtures of Methanol, tert-Butyl Alcohol and Acetonitrile
Oľga Vollárová* and Ján Benko
Department of Physical Chemistry, Comenius University, 842 15 Bratislava, Slovak Republic
Abstract
The solubility, partial molar volume and standard integral molar enthalpy of solution of cis- and trans-[CoCl2(en)2]Cl in water, aqueous methanol, aqueous tert-butyl alcohol and aqueous acetonitrile are reported. The transfer functions ∆Gt0, ∆Ht0 and T∆St0 as well as partial molar volumes are used to obtain information on the solute-solvent interactions. Results obtained are discussed in terms of differences in the surface charge distribution in isomeric coordination species.
Keywords: Complex ions; Solvation; Transfer thermodynamic functions; Partial molar volumes; Thermodynamics; Cobalt; Solubility.
References: 19 live references.
