Collect. Czech. Chem. Commun.
2002, 67, 1616-1622
https://doi.org/10.1135/cccc20021616
Synthesis of Tricarbonyl(diacetylarene)chromium and Tricarbonyl(diformylarene)chromium Complexes
Iveta Kmentová and Štefan Toma*
Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University, SK-842 15 Bratislava, Slovak Republic
Abstract
Tricarbonylchromium complexes of diacetylbenzenes and 2,2'-diacetylbiphenyl were prepared in reasonable yields by direct complexation of the starting materials. Tricarbonylchromium complexes of diformylbenzenes and 2,2'-diformylbiphenyl were prepared in good yields by the complexation of the corresponding dioxolanes followed by acidic hydrolysis of the protective groups.
Keywords: Tricarbonylchromium complexes; Arene complexes; Aldehydes; Ketones; Diacetylarenes; Diformylarenes; Biaryls; Chromium hexacarbonyl.
References: 21 live references.
