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Collect. Czech. Chem. Commun. 2006, 71, 1557-1570
https://doi.org/10.1135/cccc20061557

Kinetic Study of Hydrolysis of Benzoates. Part XXVI. Variation of the Substituent Effect with Solvent in Alkaline Hydrolysis of Substituted Alkyl Benzoates

Vilve Nummert, Mare Piirsalu and Ilmar A. Koppel*

Institute of Chemical Physics, Tartu University, Jakobi 2, 51014 Tartu, Estonia

Crossref Cited-by Linking

  • Nummert Vilve, Piirsalu Mare, Vahur Signe, Toom Lauri, Leito Ivo, Koppel Ilmar A.: Effects of neutral and charged substituents on the infrared carbonyl stretching frequencies in phenyl and alkyl benzoates in DMSO. J. Phys. Org. Chem. 2017, 30, e3608. <https://doi.org/10.1002/poc.3608>
  • Nummert Vilve, Piirsalu Mare, Koppel Ilmar A.: Prediction of ortho substituent effect in alkaline hydrolysis of substituted phenyl benzoates in aqueous acetonitrile. J. Phys. Org. Chem. 2013, 26, 352. <https://doi.org/10.1002/poc.3096>
  • Nummert Vilve, Piirsalu Mare, Koppel Ilmar A.: Prediction of ortho substituent effect in alkaline hydrolysis of phenyl esters of substituted benzoic acids in aqueous acetonitrile. cent.eur.j.chem. 2013, 11, 1964. <https://doi.org/10.2478/s11532-013-0321-5>
  • Nummert Vilve, Mäemets Vahur, Piirsalu Mare, Vahur Signe, Koppel Ilmar A.: 17O NMR study of ortho and alkyl substituent effects in substituted phenyl and alkyl esters of benzoic acids. Collect. Czech. Chem. Commun. 2011, 76, 1737. <https://doi.org/10.1135/cccc2011100>
  • Nummert Vilve, Piirsalu Mare, Koppel Ilmar A.: Influence of solvent on the ortho substituent effect in the alkaline hydrolysis of phenyl esters of substituted benzoic acids. J of Physical Organic Chem 2010, 23, 497. <https://doi.org/10.1002/poc.1628>
  • Nummert Vilve, Piirsalu Mare, Mäemets Vahur, Vahur Signe, Koppel Ilmar A.: Effect of ortho substituents on carbonyl carbon 13C NMR chemical shifts in substituted phenyl benzoates. J of Physical Organic Chem 2009, 22, 1155. <https://doi.org/10.1002/poc.1569>
  • Nummert Vilve, Piirsalu Mare, Vahur Signe, Travnikova Oksana, Koppel Ilmar A.: Kinetic study of hydrolysis of benzoates. part xxvii. ortho substituent effect in alkaline hydrolysis of phenyl esters of substituted benzoic acids in aqueous Bu4NBr. Collect. Czech. Chem. Commun. 2009, 74, 29. <https://doi.org/10.1135/cccc2008019>
  • Nummert Vilve, Piirsalu Mare, Koppel Ilmar A.: Variation of the temperature‐dependent substituent effects with solvent in alkaline hydrolysis of substituted phenyl and alkyl benzoates and phenyl tosylates. J of Physical Organic Chem 2007, 20, 778. <https://doi.org/10.1002/poc.1246>
  • Böhm Stanislav, Exner Otto: Steric effects of the alkyl groups: evaluation on isolated molecules by means of isodesmic reactions. Org. Biomol. Chem. 2007, 5, 2081. <https://doi.org/10.1039/B704459C>